4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane

نویسندگان

  • Junshan Sun
  • Yanmin Huo
  • Rentao Wu
  • Jikun Li
  • Yudao Ma
چکیده

THE TITLE COMPOUND [SYSTEMATIC NAME: 1(2)-amino-4(2)-(1-naphth-yl)-1,4(1,4)-dibenzenacyclo-hexa-phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo-phane and 1-naphthalene-boronic acid in the presence of 1,4-dioxane. It is a new cyclo-phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo-phane units are very slightly deformed from planarity as shallow boats.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008